Preheat the oven to 350F (175C) and spray an 8x8 inch pan with nonstick baking spray.
In a medium-sized bowl, whisk together the cake flour, baking powder, salt, and lemon zest. Set aside.
2 ½ cups cake flour, 2 teaspoons baking powder, ½ teaspoon salt, 1 tablespoon lemon zest
In the bowl of an electric stand mixer fitted with a paddle attachment, cream together the butter and sugar until light and fluffy. This should take about 3 minutes.
½ cup unsalted butter, ¾ cup granulated sugar
Add in the eggs one at a time, followed by the vanilla extract, sour cream, and lemon juice. Mix until everything is combined.
2 large eggs, 1 teaspoon vanilla extract, ½ cup sour cream, 2 tablespoons lemon juice
Gently add the flour mixture into the wet mixture and mix until just combined.
Pour the lemon batter into the prepared 8x8 pan, using a silicone spatula to scoop the batter from the bowl.
Bake for about 20 to 25 minutes, or until a toothpick inserted into the center of the cake comes out clean. Remove the cake from the oven and let it cool in the baking pan for about 5 minutes, before moving it to a cooling rack and allowing it to cool completely, this should take about 20 to 30 minutes.